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Honestly, IMO the hammer is the most humane way of euthanizing fish. I have only ever had to euthanize once, and it was on a male guppy that had developed fish tuberculosis. He was on his way out, and it looked like it was going to be a painful death, so I convinced my dad to do the dirty work. He grabbed the fish, layed it on a tissue, then gave it one good smack to the head. It is the most humane way. With the clove oil/vodka method, it's impossible to know whether that is painful or not. How do we know whether is makes their last couple minuted excruciatingly painful? Freezing is a big no-no. All tropical fish are tropical fish, they require warmth. That makes freezing bad full stop. Hammer is the most painless and effective way. You just fish it out. and them hit it with the hammer, imagine it as having a house dropped on top of you with considerable force. Not going to hurt, you'd just be hit. IMO it is the most respectful way to send your friend out as you can be sure they are feeling no pain. I am very sorry about your little froggy. :(
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