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I have heard that peat moss lowers pH and I think that I will try to find some to put in my filter.
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Peat moss is good, you shouldn't have any trouble finding it at a Home Depot type store. Just make sure it's pure peat moss and doesn't have any additives in it.
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I also have a few pieces of driftwood that I could use. They are pieces that I found on the Merrimack River and I was going to boil them for several hours, then let them soak for a day or so before I put them in. Should they be safe by this time?
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That should work, although personally I'm paranoid, so I'd probably throw a ghost shrimp in with the wood first as a guinea pig (shrimp are much more sensitive to chemicals and such).
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I am guessing that my kh and gh are high, because I have tried some pH 7.0 powder and it only lowered it to 7.2 with about twice the recommended dose (I did not put this water in the aquarium to be safe). That is why I figured the natural method would be more effective.
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Sounds like you do have very hard water. Unfortunately, that probably means that the natural means are not going to be very effective. Acid Buffer by Seachem may be the way to go as it lowers kh and ph. Another option is to mix R/O water from your LFS with your tap water. R/O water is very soft and acidic, and your water is very hard and alkaline, so by mixing the two, you shouldn't have any trouble finding a happy medium. That would probably be the most natural and stable.
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If it did not work, is it safe to use antibiotics in a tank with driftwood (hopefully this will lower the pH enough for them to be effective) or will the driftwood always retain some of the medication?
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It depends on the medication. You may want to boil the driftwood afterwards or at least run carbon in your filter for some time. That reminds me- have you been removing carbon from your filter before treating with medication? The carbon will render the medicine useless.
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Also, when I do water changes if the water from my tap has a higher pH than the tank (which will hopefully be lowered by the peat moss and driftwood) will this shock my fish?
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If the water chemistry isn't too different from the tap water, and you do small water changes, it should be fine. You can also pre-prepare the water by leaving it in a bucket with some peat moss for a few days.