I do not think tannins ever get bad as they are anti-bacterial and fight fungus, being already boiled it is a good idea to be using it slowly, it can last a few months I think being fresh.
I think they can lose potency after a while if they're not mixed with preservatives though? I've heard a sealed airtight container is good for at least a year.
i heard boiling it will make it loose some good nutrients and stuff in it . Can i make IAL extract by soaking the leaves with an airpump in it for 3 days?
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