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I don't recommend you try to house your fish with a tankmate in that tank. Also, for your tank you should be doing water changes every 2 - 3 days. The most likely explanation is that your tank experience an ammonia spike after adding the frog.

Start with a 100% water change and acclimatize him and add him back to the tank. If his eyes are starting to pop out, we could start conservatively by adding 1.5 tsp of Epsom salt.

Look around and see where and what antibiotics you can get, but don't jump on that yet, it's probably not going to be necessary.
 
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