As a photography student, I think I can throw in my two cents.
First of all, I do believe that it's possible to get gorgeous pictures in the betta'a actual tank, providing you have a source of light above it. Even though my camera is awful, I still manage to get the occasional good quality photo of my fish. Obviously if the fish is for sale you would do what hrutan said, but if you're just taking pictures of your pet fish, keep it in it's tank: when photographing animals you want to make sure they're comfortable and relaxed.
If your fish is scared of the camera (my Lucifer flares at it but he doesn't hide, Medusa is curious of everything and she swims right up to it), there are ways to help it overcome that. Try placing the camera somewhere near the tank so that the fish can see it, and feed it some food - if there's a particular food that it really likes such as bloodworms, use that. Continue to do this until your fish associates the presence of the camera with feeding.
Now, for the settings.
Personally, I wouldn't use flash. I feel that flash alters the colours of the fish too much, sometimes beyond the point where it can be corrected. You will also most likely get a nasty specular reflection off the glass which will jut ruin the whole image.
If you're just getting used to the camera, keep your focus on automatic. This can be found of the side of your lens. Hold the shutter release button halfway down and wait for the camera to focus on the fish before pushing it all the way down. Once you feel more confident you can start using manual focus which gives you much better control of the camera.
Make sure that your camera is set for taking images in a RAW format. This will ensure that the images are of top quality. They will take up more memory and will be much bigger than let's say, JPG, but you can always compress them later. You can usually find this in your settings under a heading "image quality" or something similar.
Keep you depth of focus shallow if you're wanting good close-up shots. I feel that using the macro setting (little flower) is a little like cheating and doesn't always give the best results. Set your camera to manual (M) and adjust your aperture to about f2.4 or f5.6: I'm not sure how low your camera goes, but both of these settings will work just as fine.
Shutter speed should be relatively fast as fish move constantly and you want a sharp photo. 1/1000 of a second should work fine, but you have to see what your camera is capable of first.
Make sure that your images aren't over or under exposed. When looking through the viewfinder, you will see a row of vertical lines at the bottom, among other information. These lines will be either on the left or right side of a thicker line: your goal is to
not have any lines on the side of this said line. You do this by adjusting the exposure with a ring (I can't remember the proper name of it) which should be located on the right hand side of the camera.
When you get your images, it's always worth to adjust them a little to make the best out of them. I'm not talking about heavy photoshopping, just simple things such as cropping, increasing the contrast and adjusting the colour temperature. If you have access to programmes that allow you to do this, great! If not, I'm sure you'll learn how to take great photos of your fish regardless of whether or not you can edit them
Edit: obviously I'm not familiar with your camera but these generally apply to all DSLRs. Also, please excuse me if some of this doesn't make sense, I'm half asleep haha.